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Caltech working to solve the world's energy problems with the help of inVia
18th November 2016
Fossil fuels are the world's main fuel source for transportation, heating and generating electricity. As a by-product, high levels of CO2 are released into the atmosphere. With the drive for sustainable energy production, a method that generates easily-stored fuel from sunlight—and absorbs CO2—is a very attractive proposition.
The California Institute of Technology (Caltech) is on a mission to find new and effective ways to produce solar fuels using only sunlight, water and carbon dioxide. A focus of this is investigating photocatalysis and light capture. Dr David A. Boyd is using Raman spectroscopy to accelerate the discovery and in-depth understanding of photocatalysts and photoactive materials for the solar-driven CO2 reduction reactions.
Dr Boyd uses a Renishaw custom designed inVia Raman Microscope, installed at the Joint Centre for Artificial Photosynthesis (JCAP). JCAP is one of the Department of Energy's Energy Innovation Hubs and is led by a team from Caltech. The High Throughput Experimentation (HTE) group aims to accelerate the identification of semiconductor materials, with appropriate band energetics, for efficient photoelectrocatalysis of solar fuel reactions. They use combinatorial materials synthesis and high-throughput electrochemistry to create and identify candidate materials. A novel example is the use of ink-jet printing to produce thousands of different combinations of metal oxide photocatalysts on a single 4” × 6” substrate, prior to electrochemical studies.
Dr Boyd said, “The inVia system is a natural fit to assist in the identification and characterisation of metal oxide catalysts. Given our sample sizes and the need to differentiate a number of possible material phases, we require large area mapping and advanced analysis capabilities. The Renishaw Empty Modelling tools have been especially invaluable; they have enabled us to derive basic spectra from the Raman imaging datasets, which could then be identified and matched to reference patterns from the literature and the RRUFF mineral database. This has allowed us to identify materials that are strong performers.”
Dr Boyd and his colleagues have recently published a paper on this work in the RSC Journal of Materials Chemistry A, ‘Solar Fuels Photoanodes Prepared by Inkjet Printing of Copper Vanadates.' This paper describes the processing and characterisation of these exciting new materials that address the demanding requirements needed to perform the photoelectrocatalysis oxygen evolution reaction. A key element of this work is Raman imaging, with associated data processing and visualisation, which has enabled phase mapping of the array of compositions. This has led to the identification of promising photoanodes for solar fuel applications.
Please visit www.renishaw.com/materialsscience for further details on how Renishaw's inVia confocal Raman microscope is being used in materials characterisation.
1 P. Newhouse, D.A. Boyd, A. Shinde, D. Guevarra, L. Zhou, E. Soedarmadji, G. Li, J. Neaton and J. Gregoire, J. Mater. Chem.A, 2016, DOI: 10.1039/C6TA01252C.
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